Could there be organic matter on Mars?

Micrometeorites are some of the most abundant material to fall on Mars, and contain organic carbon that may form chloromethane when heated.

Micrometeorites are some of the most abundant material to fall on Mars, and contain organic carbon that may form chloromethane when heated.  (Bastian Baecker (University of Heidelberg and Max Planck Institute for Chemistry) and Luigi Folco (University of Pisa))

The origins of organic matter found by Mars lander missions have long been debated, but a new study suggests a way to find out whether these chemicals of life came from the Red Planet or elsewhere.

Several Mars lander missions have detected chloromethane, a chemical sometimes produced by living organisms, but most scientists think the findings were contamination from Earth.

Now, a team of researchers has replicated these experiments on a meteorite found on Earth, and found that it produced chloromethane from organic materials contained in the space rock. The findings suggest the chloromethane on Mars may have come from meteorite debris on the planet's surface or the Martian soil itself, rather than from Earth. [The Search for Life on Mars (Photo Timeline)]

NASA's Viking landers descended onto the Red Planet in 1976. The Viking 1 lander, the first of the two, detected chloromethane in a sample of soil it baked in a small oven on board. The second lander, Viking 2, did not detect chloromethane, but did find traces of dichloromethane, another organic compound. However, scientists dismissed the findings, saying they were contamination from Earth.

More recently, NASA's Curiosity rover found traces of chloromethane in soil heated in one of its own chemistry instruments. Again, researchers claimed the chemicals were nothing more than terrestrial contamination, partly because it wasn't clear whether such chemicals could form on their own.

Frank Keppler, a biogeochemist at the University of Heidelberg in Germany, led a study to analyze the Murchison meteorite that landed in Australia in 1969. He reasoned that if he could understand how chloromethanes formed from this meteorite, he might be able to shed some light on whether the ones found on Mars came from Earth, from other meteorites or from the Red Planet itself — and possibly from life.

Mars is constantly pummeled by small rocks called micrometeorites. "Every year, about 50,000 tons fall on the Martian surface," Keppler said. Most of these are carbonaceous, meaning they contain carbon, an essential building block for life.

The researchers heated up material from the Murchison meteorite to temperatures of up to 750 degrees Fahrenheit, similar to those in the Viking and Curiosity experiments, and sure enough, they found chloromethane. They knew it wasn't contamination from Earth because it had a different chemical fingerprint.

Chemical elements come in different forms, called isotopes. The researchers looked at the isotope signatures of carbon and nitrogen in the chloromethane from the meteorite, and they didn't match those found on Earth. Heating up the chemicals produced similar amounts of chloromethane as those found by Viking and Curiosity, suggesting the same process may have occurred with micrometeorites on the Red Planet.

To determine whether the chloromethane on Mars came from Earth, from meteorites or from the Martian soil, scientists could measure its isotopic signature, Keppler said. At the moment, the landers on Mars (including Curiosity) do not have the tools to measure these isotopes, but perhaps future missions will, he said.

Based on the findings, the presence of chloromethane is a "clear sign" that organic matter exists on Mars, Keppler said. This doesn't necessarily suggest the organic matter came from life, he said, "but we cannot exclude it."

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