Former Saints defensive end Will Smith is dead after he and his wife were shot in a road-rage attack late Saturday night in New Orleans.

The shootings took place during an argument that occured when Smith's SUV was rear-ended at an intersection, police said. Smith died behind the wheel while his wife, Racquel, was wounded in the leg. A 30-year-old man and the gun are in custody, authorities announced.

Photo: Former #Saint Pierre Thomas distraught at scene of Will Smith's murder on #NewOrleans pic.twitter.com/3BbaEYI1lX

— Michael DeMocker (@MichaelDeMocker) April 10, 2016

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Photo gallery from shooting death of #Saints captain Will Smith is now posted. https://t.co/4myfnwB6ut pic.twitter.com/XMiKrFSOHC

— Michael DeMocker (@MichaelDeMocker) April 10, 2016

Witnesses: #Saints Will Smith shot to death in car on Camp St, wife wounded pic.twitter.com/JNoFmnZRXk

— Michael DeMocker (@MichaelDeMocker) April 10, 2016

Photo:
Will Smith 1-hour before being shot & killed, w/Pierre Thomas & former NOPD commander Billy Ceravolo.
So sad. pic.twitter.com/PMFpRm3vOl

— Fletcher Mackel (@FletcherMackel) April 10, 2016

Former teammates and players around the league expressed shock and grief.

RIP WILL SMITH.. #NewOrleans

— Tyrann Mathieu (@Mathieu_Era) April 10, 2016

Devastated. Lord please be with the Smith family at this tragic time. Nonsense man...

— Mark Ingram II (@MarkIngram22) April 10, 2016

praying for the wife and family of @Saints will smith... RIP

— Harry Connick, Jr. (@HarryConnickJR) April 10, 2016

Sad to hear the terrible news about Will Smith, he was a great person and I will forever remember the times I had with him. #RIPWillSmith

— Rob Ninkovich (@ninko50) April 10, 2016

Man. The #Saints community has lost former DE Will Smith to gun violence. Another tragedy. Deepest condolences. #RIP https://t.co/rGBUeKjJe8

— Rachel Nichols (@Rachel__Nichols) April 10, 2016

Wow life's too short, RIP Will Smith appreciate all the knowledge u gave me. Prayers up for your family 🙏🏾

— Glenn Dorsey (@GlennDorsey72) April 10, 2016

RIP Will Smith #Saints its sad man that's two brothers lost this year.

— Strizzy (@JaelenStrong) April 10, 2016

Horrific news. Former Saints, Ohio State DE Will Smith shot to death in N. Orleans. End result of verbal spat following traffic collision.

— Linda Cohn (@lindacohn) April 10, 2016

Smith, 34, was a five-time defensive captain during his 10 seasons with the Saints, leading the team in sacks for three straight years (2005-07) and finishing with 67.5 in his career, fourth-most in team history.

He experienced the highs and lows -- €” winning a Super Bowl in 2009 and being suspended four games in 2012 following the NFL's investigation into the Bountygate scandal. His suspension was later overturned.

Smith tore an ACL in the 2013 preseason and was released following the season in a cost-cutting move. Still, he thanked the Saints and said New Orleans had become home to his family.

"While it was always my dream to retire as a member of the New Orleans Saints, I recognize that the NFL remains a business first. I will always be grateful to Mr. (Tom) Benson, Mr. (Mickey) Loomis, and Coach (Sean) Payton for the opportunity they gave me to play the sport I love in front of football's greatest fans, amongst some of my best friends. ...

"We accomplished great things during my time with the Saints, including winning the first Super Bowl in franchise history, and I am proud of my contributions during the decade I wore black and gold. My wife Racquel and I will continue our commitment to improving lives for New Orleans' youth no matter where my next stop in professional football takes me. I'm in good spirits, thankful and focused on training. My family and I welcome the next chapter in our NFL life. Who Dat!"

Smith was drafted 18th overall in 2004 out of Ohio State, where he was named a member of the All-Decade Team.