Ortiz, 36, wore a white lace gown at Saturday's ceremony, which took place in an oceanview dining room of the Horned Dorset Primavera Hotel in Rincon, on the Caribbean island's west coast, manager Wilhelm Sack said Monday.
Among the 80 guests were Ortiz's cast members from "Ugly Betty," including star America Ferrera.
"I would call it a mixture between Hollywood and Puerto Rico," Sack said. "It was very glamorous."
Ortiz was honored for her role in the series with the best supporting actress award at the 2007 ALMA Awards, dedicated to achievements by Hispanic artists.
Lebenzon, 37, is a guitarist for the rock group Everything Is Energy.