It's all in the lips. Angelina Jolie (search) has been named the sexiest woman in the world by FHM (search) magazine. It is Jolie's first time at the top of the annual readers' poll by the American edition of the men's magazine.

"Angelina Jolie embodies everything that our readers find incredibly sexy," editor in chief Scott Gramling said in a statement Wednesday. "Not only is she stunning, she is intelligent, outspoken and passionate in her beliefs and well-respected the world over for her tireless efforts on behalf of the world's refugee children."

The 29-year-old actress is a goodwill ambassador for the United Nations (search) refugee agency and the mother of Cambodia-born Maddox, whom she adopted. Jolie said she plans to adopt again and her son wants an "African brother."

More than 15 million votes were cast worldwide in the poll.

After Jolie, readers ranked, in order, Jennifer Garner, Paris Hilton, Charlize Theron, Halle Berry, Alyssa Milano, Teri Hatcher, Pamela Anderson, Scarlett Johansson and Lindsay Lohan.

Other notables on the list include British actress Keira Knightley, Russian tennis star Maria Sharapova and Latin actress Sofia Vergara.

Last year's winner, Britney Spears, didn't even make the list of 100.

The sexiest women in the world list is published as a supplement to FHM's May issue, on newsstands April 5.